Collaborative Research Center/Transregio 63
"Integrated Chemical Processes in Liquid Multiphase Systems"
Kraume, Matthias, Enders, Sabine, Drews, Anja, Schomäcker, Reinhard, Engell, Sebastian and Sundmacher, Kai. Integrated Chemical Processes in Liquid Multiphase Systems: From Chemical Reaction to Process Design and Operation, Berlin, Boston: De Gruyter, 2022. [DOI: 0.1515/9783110709858]
Hamel, C.; Seidel-Morgenstern, A. Potential of membranes for process intensification of selective oxidations on catalyst, reactor and total process level. Chemie Ingenieur Technik, 94, 1-2, 1-15, 2022. [DOI: 10.1002/cite.202100130]
Huxoll, F.; Kampwerth, A.; Seidensticker, T.; Vogt, D.; Sadowski, G. Predicting Solvent Effects on Homogeneity and Kinetics of the Hydroaminomethylation: A Thermodynamic Approach Using PC-SAFT. Industrial & Engineering Chemistry Research, 61 (5), 2323-2332, 2022. [DOI: 10.1021/acs.iecr.1c03891]
Janus, T.; Riedl, F.; Engell, S. Generation and Benefit of Surrogate Models for Blackbox Chemical Flowsheet Optimization. Computer-aided Chemical Engineering, 49, 1561-1566, 2022. [conference paper]
Jameel, F.; Stein, M. The many roles of solvent in homogeneous catalysis - The reductive amination showcase. Journal of Catalysis, 405, 24-34, 2022. [DOI:10.1016/j.jcat.2021.11.010]
Keßler, T.; Kunde, C.; Linke, S.; Sundmacher, K.; Kienle, A. Integrated Computer-Aided Molecular and Process Design: Green Solvents for the Hydroformylation of Long-Chain Olefines. Chemical Engineering Science, 249, 117243, 2022 [DOI:10.1016/j.ces.2021.117243]
Kortuz, W.; Kirschtowski, S.; Seidel-Morgenstern, A.; Hamel, C. Kinetics of the Rhodium-Catalyzed Hydroaminomethylation of 1-Decene in a Thermomorphic Solvent System. Chemie Ingenieur Technik, (in press), 2022. [DOI:10.1002/cite.202100180]
Kunde, C.; Méndez M.; Kienle A. Deterministic global optimization of multistage layer melt crystallization using surrogate models and reduced space formulations. Computer-Aided Chemical Engineering, 51, 727-732, 2022. [in press ISBN: 9780323958790]
Mueller, I.; Runne, E.; Hamel, C. Comparative Study on Mechanistic Kinetic Modeling of the Enzymatic Synthesis of Galacto-Oligosaccharides. Chemie Ingenieur Technik, (in press), 2022. [DOI:10.1002/cite.202100190]
Petzold, M.; Paul, N.; Hohl, L.; Böhm, L.; Kraume, M. Gas/Liquid Mass Transfer Phenomena in Micellar Multiphase Systems. Chemical Engineering & Processing: Process Intensification, 171, 108547, 2022. [DOI: 10.1016/j.cep.2021.108547]
Stock, S.; von Klitzing, R. Microgels at Droplet Interfaces of Water-in-Oil Emulsions - Challenges and Progress. Current Opinion in Colloid & Interface Science, 58, 101561, 2022. [DOI:10.1016/j.cocis.2021.101561]
Afraz, N.; Adi, A.; Hecht, K. The effect of diffusion on mass transfer in a laminar falling film: Observation versus theory. Chemical Engineering Science 232, 116363, 2021. [DOI:10.1016/j.ces.2020.116363]
Boz, E.; Stein M. Accurate Receptor-Ligand Binding Free Energies from Fast QM Conformational Chemical Space Sampling. Int. J. Mol. Sci. 22, 6, 3078, 2021. [DOI:10.3390/ijms22063078]
Brune, A.; Geschke, A.; Seidel-Morgenstern, A.; Hamel, C. Modelling and Simulation of Catalyst Deactivation during Propane Dehydrogenation - Comparison of Different Modelling Approaches. Chemical Engineering and Processing: Process Intensification, 108689, 2021. [DOI:10.1016/j.cep.2021.108689]
Gottu Mukkula, A.R.; Engell, S. Handling Measurement Delay in Iterative Real-Time Optimization Methods. Processes, 9, 1800, 2021. [DOI:doi.org/10.3390/pr9101800]
Heine, J. S.; Schulz, J. M.; Junne, H.; Böhm, L.; Kraume, M.; Bart, H. J. Real‐Time Visualization of Internal and External Concentration Fields in Multiphase Systems via Laser‐induced Fluorescence and Rainbow Schlieren Deflectometry During and After Droplet Production. Chem. Ing. Tech., 93 (1–2, 1–12) , 2021. [DOI:10.1002/cite.202000135]
Huxoll, F.; Jameel, F.; Bianga, J.; Seidensticker, T.; Stein, M.; Sadowski, G.; Vogt, D.; Solvent Selection in Homogeneous Catalysis—Optimization of Kinetics and Reaction Performance. ACS Catalysis 11, 2, 590-594, 2021. [DOI:10.1021/acscatal.0c04431]
Huxoll, F.; Heyng, M.; Andreeva, I. V.; Verevkin, S. P.; Sadowski, G. Thermodynamic Properties of Biogenic Amines and Their Solutions. Journal of Chemical & Engineering Data, 66 (7), 2822-2831, 2021. [DOI: 10.1021/acs.jced.1c00202]
Huxoll, F.; Schlüter, S.; Budde, R.; Skiborowski, M.; Petzold, M.; Böhm, L.; Kraume, M.; Sadowski, G. Phase Equilibria for the Hydroaminomethylation of 1-Decene. Journal of Chemical & Engineering Data, 66 (12), 4484-4495, 2021. [DOI: 10.1021/acs.jced.1c00561]
Jameel, F. Stein, M. Solvent effects in hydroformylation of long-chain olefins, Molecular Catalysis, 503, 111429, 2021.[DOI:10.1016/j.mcat.2021.111429]
Janus, T.; Engell, S. Iterative Process Design with Surrogate-Assisted Global Flowsheet Optimization. Chemie Ingenieur Technik, 93, 2018-2028, 2021. [DOI:10.1002/cite.202100095]
Kaiser, S.; Menzel, T.; Engell, S. Focusing experiments in the early phase process design by process optimization and global sensitivity analysis. Computer Aided Chemical Engineering, 50, 899-904, 2021. [DOI:10.1016/B978-0-323-88506-5.50139-X]
Kirschtowski, S.; Jameel, F.; Stein, M.; Seidel-Morgenstern A.; Hamel, C. Kinetics of the Reductive Amination of 1-Undecanal in Thermomorphic Multicomponent System, Chemical Engineering Science, 230, 116187, 2021. [DOI:10.1016/j.ces.2020.116187]
Kempin, M. V.; Drews A. Organic Solvent Nanofiltration of Water-in-Oil Pickering Emulsions - What Influences Permeability? Membranes, 11, 864, 2021. [DOI:10.3390/membranes11110864]
Kempin, M. V.; Drews, A. What Governs Pickering Emulsion Properties During Preparation via Batch Rotor‐Stator Homogenizers? Chem. Ing. Tech. 93 (1–2), 311-317, 2021. [DOI:10.1002/cite.202000130]
Künnemann, K. U.; Weber, D.; Becquet, C.; Tilloy, S.; Monflier, E.; Seidensticker, T.; Vogt, D. Aqueous biphasic hydroaminomethylation enabled by methylated cyclodextrins: sensitivity analysis for transfer into a continuous process. ACS sustainable chemistry & engineering, 9, 273–283, 2021. [DOI:10.1021/acssuschemeng.0c07125]
Mansour, M.; Kasetti, S.; Thévenin, D.; Nigam, K. D. P.; Zähringer, K. Numerical study of the separation of two immiscible liquids in helical and straight pipes. Chemical Engineering and Processing - Process Intensification, 108654, 2021.[DOI:doi.org/10.1016/j.cep.2021.108654]
Müller, C., Kováts, P. and Zähringer, K. Experimental characterization of mixing and flow field in the liquid plugs of gas–liquid flow in a helically coiled reactor. Experiments in Fluids, 62 (9), 190, 2021. [Doi: 10.1007/s00348-021-03284-7]
Pandey, I. K.; Agarwal, T; Stein, M.; Kaur-Ghumaan, S. Switching Site Reactivity in Hydrogenase Model Systems by Introducing a Pendant Amine Ligand. ACS Omega Article, 6, 6, 4192–4203, 2021. [DOI:10.1021/acsomega.0c04901]
Sanchez Medina, E. I.; Linke, S.; Sundmacher, K. Prediction of Bioconcentration factors (BCF) using Graph Neural Networks. Computer Aided Chemical Engineering, 50, 991-997, 2021. [DOI:10.1016/B978-0-323-88506-5.50153-4]
Schlüter, S.; Künnemann, K. U.; Freis, M.; Roth, T.; Vogt, D.; Dreimann, J. M.; Skiborowski, M. Continuous co-product separation by organic solvent nanofiltration for the hydroaminomethylation in a thermomorphic multiphase system, Chemical Engineering Journal, 409, 128219, 2021. [DOI: 10.1016/j.cej.2020.128219]
Schulz, J. M.; Petzold, M.; Böhm, L.; Kraume, M. Fluid Dynamics and Mass Transfer in Technical Grade Liquid‐Liquid Systems. Part 2: Impact of Interfacial Effects and Impurities. Chemie Ingenieur Technik, 93, 8, 121-1222, 2021 [DOI:10.1002/cite.202000247]
Schulz, J. M.; Petzold, M.; Böhm, L.; Kraume, M. Fluid Dynamics and Mass Transfer in Technical Grade Liquid‐Liquid Systems. Part 1: Sedimentation of Single Droplets in Absence of Interfacial Effects. Chemie Ingenieur Technik, 93, 3, 353-363, 2021 [DOI:10.1002/cite.202000246]
Stock, S.; Jakob, F.; Röhl, S.; Gräff, K.; Kühnhammer, M.; Hondow, N.; Micklethwaite, S.; Kraume, M.; von Klitzing, R. Exploring Water in Oil Emulsions simultaneously stabilized by solid hydrophobic Silica Nanospheres and hydrophilic soft PNIPAM Microgel. Soft matter 17, 8258–8268, 2021. [DOI:10.1039/D1SM00942G]
Stock, S.; Schlander, A.; Kempin, M.; Geisler, R.; Stehl, D.; Spanheimer, K.; Hondow, N.; Micklethwaite, S.; Weber, A.; Schomäcker, R.; Drews, A.; Gallei, M.; von Klitzing, R.The quantitative impact of fluid vs. solid interfaces on the catalytic performance of pickering emulsions, Phys. Chem. Chem. Phys., 23, 2355-2367, 2021. [DOI:10.1039/D0CP06030E]
Walter, J.P.; Brune, A.; Seidel-Morgenstern, A.; Hamel, C. Stationary and Transient Modelling of a Heat-Integrated Membrane Reactor for the Propane Dehydrogenation. Catalysts, 11, 1056, 2021. [DOI:10.3390/catal11091056]
Weber, A.; Isbrücker, P.; Schmidt, M.; Schomäcker, R. Ionic Liquids as Surfactants in Aqueous Multiphase Systems for the Pd-Catalyzed Hydrocarboxylation. Chem. Ing. Tech. 93 (1-2), 201-207, 2021. [DOI:10.1002/cite.202000165]
Weber, A.; Porthun, L.; Schomäcker, R. Rh-Catalyzed Reductive Amination of Undecanal in an Aqueous Microemulsion System Using a Non-Ionic Surfactant. Catalysts, 11, 1223, 2021 [DOI: 10.3390/catal11101223]
Bianga, J.; Herrmann, N.; Schurm, L.; Gaide, T.; Dreimann, J.M.; Vogt, D.; Seidensticker, T. Improvement of Productivity for Aqueous Biphasic Hydroformylation of Methyl 10‐Undecenoate – A Detailed Phase Investigation. Eur. J. Lipid Sci.Technol., 122, 1900317, 2020. [DOI:10.1002/ejlt.201900317]
Bianga, J; Kopplin, N.; Hülsmann, J.; Vogt, D.; Seidensticker, T. Rhodium‐Catalysed Reductive Amination for the Synthesis of Tertiary Amines. Adv. Synth. Catal., 362, 4415-4424, 2020. [DOI:10.1002/adsc.202000746]
Bianga, J.; Künnemann, K. U.; Goclik, L.; Schurm, L.; Vogt, D.; Seidensticker, T. Tandem Catalytic Amine Synthesis from Alkenes in Continuous Flow Enabled by Integrated Catalyst Recycling. ACS Catalysis., 10, 6463–6472, 2020. [DOI:10.1021/acscatal.0c01465]
Brune, A.; Seidel-Morgenstern, A.; Hamel, C. Analysis and Model-Based Description of Deactivation and Regeneration of a VOx Catalyst for Selective Dehydrogenation of Propane, Catalysts – Special Issue: Design of Heterogeneous Catalysts and Adsorbens, 10, 1374, 2020. [DOI:10.3390/catal10121374]
Esche, E; Repke, J.U. Dynamic Process Operation Under Demand Response – A Review of Methods and Tools. Chem. Ing. Tech. 92 (12), 898–1909, 2020. [DOI:10.1002/cite.202000091]
Felischak, M.; Wolff, T.; Alvarado Perea, L.; Seidel-Morgenstern, A.; Hamel, C. Detailed Kinetic Model for the Reaction of Ethene to Propene on Ni/AlMCM-41. Chem. Ing. Tech., 92 (5), 564-574, 2020. [DOI:10.1002/cite.201900139]
Gottu Mukkula, A. R.; Engell, S. Guaranteed model adequacy for modifier adaptation with quadratic approximation. 19th European Control Conference(ECC), 1037-1042, 2020. [DOI:10.23919/ECC51009.2020.9143625]
Hecht, K. J.; Velagala, S.; Easo, D. A.; Saleem, M. A.; Krause, U. Influence of Wettability on Bubble Formation from Submerged Orifices. Industrial & Engineering Chemistry Research Article, 59 (9), 4071-4078, 2020. [DOI:10.1021/acs.iecr.9b04222]
Herrmann, N.; Bianga, J.; Palten, M.; Riemer, T.; Vogt, D.; Dreimann, J.M.; Seidensticker, T. Improving Aqueous Biphasic Hydroformylation of Unsaturated Oleochemicals Using a Jet‐Loop‐Reactor. Eur. J. Lipid Sci. Technol., 122, 1900166, 2020. [DOI:10.1002/ejlt.201900166]
Herrmann, N.; Köhnke, K.; Seidensticker, T. Selective Product Crystallization for Concurrent Product Separation and Catalyst Recycling in the Isomerizing Methoxycarbonylation of Methyl Oleate. ACS Sustainable Chemistry & Engineering, 8 (29), 10633-10638, 2020. [DOI: 10.1021/acssuschemeng.0c03432]
Haarmann, N.; Reinhardt, A.; Danzer, A.; Sadowski, G.; Enders S. Modeling of Interfacial Tensions of Long-Chain Molecules and Related Mixtures Using Perturbed Chain-Statistical Associating Fluid Theory and the Density Gradient Theory. J. Chem. Eng., 65 (3), 1005–1018, 2020. [DOI:10.1021/acs.jced.9b00339]
Kaiser, S.; Engell, S. Integrating Superstructure Optimization under Uncertainty and Optimal Experimental Design in early Stage Process Development. Computer Aided Chemical Engineering, 48, 799-804, 2020. [DOI:10.1016/B978-0-12-823377-1.50134-8]
Kempin, M.V.; Kraume, M.; Drews, A. W/O Pickering emulsion preparation using a batch rotor-stator mixer - influence on rheology, drop size distribution and filtration behavior, J. Coll. Interf. Sci., 573, 135-149, 2020. [DOI:10.1016/j.jcis.2020.03.103]
Kempin, M.V.; Stock, S.; von Klitzing R.; Kraume, M.; Drews, A. Influence of particle type and concentration on the ultrafiltration behavior of nanoparticle stabilized Pickering emulsions and suspensions. Separation and Purification Technology, 252, 117457, 2020. [DOI:10.1016/j.seppur.2020.117457]
Keßler, T.; Kunde, C.; Linke, S.; McBride, K.; Sundmacher, K.; Kienle, A. Computer Aided Molecular Design of Green Solvents for the Hydroformylation of Long-Chain Olefines; Computer Aided Chemical Engineering, 48, 745-750, 2020. [DOI:10.1016/B978-0-12-823377-1.50125-7]
Kirschtowski, S.; Kadar, C.; Seidel-Morgenstern, A.; Hamel C. Kinetic Modeling of Rhodium-Catalyzed Reductive Amination of Undecanal in Different Solvent Systems. Chem. Ing. Tech., 92 (5), 582-588, 2020. [DOI:10.1002/cite.201900135]
Kováts, P.; Martins, F.; Mansour, M.; Thévenin, D.; Zähringer, K.: Tomographic PIV measurements and RANS simulations of secondary flows inside a horizontally positioned helically coiled tube. Experiments in Fluids, 61, 117, 2020. [DOI:10.1007/s00348-020-02950-6]
Kováts, P.; Velten, C.; Mansour, M.; Thevenin, D.; Zahringer, K. Mixing characterization in different helically coiled configurations by laser-induced fluorescence. Experiments in Fluids. 61, 203, 2020. [DOI:10.1007/s00348-020-03035-0]
Kuehne, I. A.; Barker, A.; Zhang, F.; Stamenov, P.; O'Doherty, O.; Müller-Bunz, H.; Stein, M.; Rodriguez, B. J.; MORGAN, G. G. Modulation of Jahn-Teller Distortion and Electromechanical Response in a Mn<sup>3+</sup> Spin Crossover Complex. J. Phys.: Condens. Matter, 32, 404002, 2020. [DOI:10.1088/1361-648X/ab82d1]
Künnemann, K. U.; Bianga, J.; Scheel, R.; Seidensticker, T.; Dreimann, J. M.; Vogt, D. Process Development for the Rhodium-Catalyzed Reductive Amination in a Thermomorphic Multiphase System. Org. Process Res. Dev. 24, 1, 41-49, 2020. [DOI:10.1021/acs.oprd.9b00409]
Künnemann, K. U.; Gumbiowski, N.; Müller, P.; Jirmann, Y.; Dreimann, J. M.; Vogt, D. Chemometrics in the Homogeneously Catalyzed Reductive Amination: Combining In Situ Fourier-Transform Infrared Spectroscopy and Band-Target Entropy Minimization. Industrial & Engineering Chemistry Research 59 (19), 9055-9065, 2020. [DOI:10.1021/acs.iecr.0c01527]
Künnemann, K. U.; Schurm, L.; Lange, D.; Seidensticker, T.; Tilloy, S.; Monflier, E.; Vogt, D.; Dreimann, J. M. Continuous hydroformylation of 1-decene in an aqueous biphasic system enabled by methylated cyclodextrins. Green Chem. 22, 3809, 2020. [DOI:10.1039/D0GC00820F]
Linke, S.; McBride, K.; Sundmacher, K. Systematic Green Solvent Selection for the Hydroformylation of Long-Chain Alkenes. ACS Sustainable Chemistry & Engineering, 8 (29), 10795-10811, 2020. [DOI:10.1021/acssuschemeng.0c02611]
Mansour, M.; Khot, P.; Kováts, P.; Thévenin, D.; Zähringer, K.; Janiga, G. Impact of computational domain discretization and gradient limiters on CFD results concerning liquid mixing in a helical pipe. Chem. Eng. Sci., 383, 123121, 2020. [DOI:10.1016/j.cej.2019.123121]
Mansour, M.; Khot, P.; Thévenin, D.; Nigam, K. D. P.; Zähringer, K. Optimal Reynolds number for liquid-liquid mixing in helical pipes. Chemical Engineering Science, 214, 114522, 2020. [DOI:10.1016/j.ces.2018.09.046]
Mansour, M.; Zähringer, K.; Nigam, K. D.P.; Thévenin, D.; Janiga, G. Multi-objective optimization of liquid-liquid mixing in helical pipes using Genetic Algorithms coupled with Computational Fluid Dynamics. Chemical Engineering Journal, 391, 123570, 2020. [DOI:10.1016/j.cej.2019.123570]
Mansour, M., Landage, A., Khot, P., Nigam, K. D. P., Janiga, G., Thévenin, D. and Zähringer, K.: Numerical Study of Gas–Liquid Two-Phase Flow Regimes for Upward Flow in a Helical Pipe. Industrial & Engineering Chemistry Research, 59 (9), 3873-3886, 2020. [DOI:/10.1021/acs.iecr.9b05268]
Mansour, M.; Thévenin, D.; Zähringer, K.: Numerical study of flow mixing and heat transfer in helical pipes, coiled flow inverters and a novel coiled configuration. Chemical Engineering Science, 221, 115690, 2020. [DOI:10.1016/j.ces.2020.115690]
McBride, K.; Edgar Ivan Sanchez Medina, E. I.; Sundmacher, K. Hybrid Semi-parametric Modeling in Separation Processes: A Review. Chem. Ing. Tech. 92 (7), 1-15, 2020. [DOI:10.1002/cite.202000025]
Reinhard, A.; Haarmann, N.; Sadowski, G.; Enders, S. Application of PC-SAFT and DGT for the Prediction of Self-Assembly. J. Chem. Eng. Data 2020, 65, 12, 5897–5908. [DOI: 10.1021/acs.jced.0c00781]
Rivas D. F.; Boffito D. C.; Faria-Albanese J.; Glassey J.; Afraz N.; Akse H.; Boodhoo K. V. K.; Bos R.;Cantin J.; Chiang Y. W.; Commenge J. M.; Dubois J. L.; Galli F.; Gueneau J. P.; Harmsen J.; Kalra S.; Keil F. J.; Morales-Menendez R.; Navarro-Brull F. J.; Noël T.; Ogden K.; Patience G. S.; Reay D.; Santos R. M.; Smith-Schoettker A.; Stankiewicz A. I.; Berg H. V. D.; Gerven T. V.; Gestel J. V.; Stelt M. V. D.; Ven M. V. D.; Weber R. S. Process intensification education contributes to sustainable development goals. Part 1. Education for Chemical Engineers. 32, 1-14, 2020. [DOI:10.1016/j.ece.2020.04.003]
Rivas D. F.; Boffito D. C.; Faria-Albanese J.; Glassey J.; Cantin J.; Afraz N.; Akse H.; Boodhoo K. V. K.; Bos R.; Chiang Y. W.; Commenge J. M.; Dubois J. L.; Galli F.; Harmsen J.; Kalra S.; Keil F. J.; Morales-Menendez R.; Navarro-Brull F. J.; Noël T.; Ogden K.; Patience G. S.; Reay D.; Santos R. M.; Smith-Schoettker A.; Stankiewicz A. I.; Berg H. V. D.; Gerven T. V.; Gestel J. V.; Stelt M. V. D.; Ven M. V. D.; Weber R. S. Process intensification education contributes to sustainable development goals. Part 2. Education for Chemical Engineers. 32, 15-24, 2020. [DOI:10.1016/j.ece.2020.05.001]
Scharzec, B.; Holtkötter, J.; Bianga, J.; Dreimann, J.M.; Vogt, D.; Skiborowski, M. Conceptual study of co-product separation from catalyst-rich recycle streams in thermomorphic multiphase systems by OSN. Chemical Engineering Research and Design. 157, 65-76, 2020. [DOI:10.1016/j.cherd.2020.02.028]
Schulz, J.M.; Junne, H.; Böhm, L.; Kraume, M. Measuring local heat transfer by application of Rainbow Schlieren Deflectometry in case of different symmetric conditions. Experimental Thermal and Fluid Science, 110, 109887, 2020. [DOI:10.1016/j.expthermflusci.2019.109887]
Stehl, D.; Skale, T.; Hohl, L.; Lvov, Y.; Koetz,J.; Kraume,M.; Drews, A.; von Klitzing. R. Oil-in-Water Pickering Emulsions Stabilized by Halloysite Clay Nanotubes Toward Efficient Filterability. ACS Applied Nano Materials. 3, 12, 11743–11751, 2020.. [DOI:10.1021/acsanm.0c02205]
Terhorst, M.; Kampwerth, A.; Marschand, A.; Vogt, D.; Vorholt, A.; Seidensticker, T. Facile Catalyst Recycling by Thermomorphic Behaviour Avoiding Organic Solvents – A Reactive Ionic Liquid in the Homogeneously Pd-Catalysed Telomerisation of the Renewable b-Myrcene. Catal. Sci. Technol., 10, 1827, 2020, [DOI:10.1039/C9CY02569C]
Terhorst, M.; Heider, C.; Vorholt, A.; Vogt, D.; Seidensticker, T. Productivity Leap in the Homogeneous Ruthenium-Catalyzed Alcohol Amination through Catalyst Recycling Avoiding Volatile Organic Solvents. ACS Sustainable Chem. Eng., 8, 9962−9967, 2020. [DOI:10.1021/acssuschemeng.0c03413]
Terhorst, M.; Plass, C.; Hinzmann, A.; Guntermann, A.; Jolmes, T.; Rösler, J.; Panke, D.; Gröger, H.; Vogt, D.; Vorholt, A. J.; Seidensticker, T. One-pot synthesis of aldoximes from alkenes via Rh-catalysed hydroformylation in an aqueous solvent system.Green Chem. 22, 7974-7982, 2020. DOI:[DOI:10.1039/D0GC03141K]
Waltermann, T.; Grueters, T.; Muenchrath, D.; Skiborowski M. Efficient optimization-based design of energy-integrated azeotropic distillation processes, Computers & Chemical Engineering, 133, 106676, 2020. [DOI:10.1016/j.compchemeng.2019.106676]
Waltermann, T.; Schlueter, S.; Benfer, R.; Knoesche, C.; Górak, A.; Skiborowski, M. Model Discrimination for Multicomponent Distillation – A Geometrical Approach for Total Reflux. Chemie Ingenieur Technik, 92 (7), 1–18, 2020. [DOI:10.1002/cite.202000026]
Bianga, J.; Künnemann K.U.; Gaide, T.; Vorholt, A.J.; Seidensticker, T.; Dreimann, J.M.; Vogt, D.Thermomorphic Multiphase Systems: Switchable Solvent Mixtures for the Recovery of Homogeneous Catalysts in Batch and Flow Processes. Chem. Eur. J., 25, 11586-11608, 2019. [doi.org/10.1002/chem.201902154]
Böhm, L.; Hohl, L.; Bliatsiou, C.; Kraume, M. Multiphase Stirred Tank Bioreactors – New Geometrical Concepts and Scale-up Approaches. Chem. Ing. Tech., 91(12), 1-24, 2019. [DOI: 10.1002/cite.201900165]
Brune, A.; Wolff, T.; Seidel‐Morgenstern, A.; Hamel, C. Analysis of Membrane Reactors for Integrated Coupling of Oxidative and Thermal Dehydrogenation of Propane; Chem. Ing. Tech., 91(9), 645, 2019. [DOI: 10.1002/cite.201800184]
Dreimann, J. M.; Kohls, E.; Warmeling, H. F. W.; Stein, M.; Guo, L. F.; Garland, M.; Dinh, T. N.; Vorholt, A. J. In Situ Infrared Spectroscopy as a Tool for Monitoring Molecular Catalyst for Hydroformylation in Continuous Processes. ACS Catal., 9, 4308–4319, 2019. DOI: 10.1021/acscatal.8b05066
Felischak, M.; Wolff, T.; Alvarado Perea, L.; Seidel-Morgenstern, A.; Hamel, C. : Influence of process parameters on single bed Ni/(Al)MCM-41 for the ethene to propene reaction. Chem. Eng. Sci., 201, 2019. [doi.org/10.1016/j.ces.2019.115246]
Gottu Mukkula, A.R.; Ahmad, A.; Engell, S. Start-up and shut-down conditions for iterative real-time optimization methods. 6th Indian Control Conference (ICC), 158–163, 2019. [DOI:10.1109/ICC47138.2019.9123183]
Haarmann, N.; Sosa, A.; Ortega, J.; Sadowski, G., Measurement and Prediction of Excess Properties of Binary Mixtures Methyl Decanoate + an Even-Numbered n-Alkane (C6 - C12) at 298.15 K. Journal of Chemical & Engineering Data, 2019. [DOI: 10.1021/acs.jced.9b00185]
Haarmann, N.; Siewert, R.; Samarov, A. A.; Verevkin, S. P.; Held, C.; Sadowski, G. Thermodynamic Properties of Systems Comprising Esters: Experimental Data and Modeling with PC-SAFT and SAFT-γ Mie. Industrial & Engineering Chemistry Research, 58(16), 6841-6849, 2019. [DOI: 10.1021/acs.iecr.9b00714]
Haarmann, N.; Enders, S.; Sadowski, G., Heterosegmental Modeling of Long-Chain Molecules and Related Mixtures Using PC-SAFT: 2. Associating Compounds. Industrial & Engineering Chemistry Research, 58(11), 4625-4643, 2019. [DOI: 10.1021/acs.iecr.9b00157]
Hernández, R. and Engell, S.: Economics Optimizing Control with Model Mismatch Based on Modifier Adaptation. In: Proc. of the 12th IFAC symposium on Dynamics and Control of Process Systems (DYCOPS), Brazil, 2019.
Hohl, L., Röder, V.; Kraume, M.: Dispersion and phase separation of water-oil-amphiphile systems in stirred tanks. Chem. Eng. Tech. 42, 1-14, 2019. [DOI: 10.1002/ceat.201800743]
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Merchan, V.A., Tolksdorf, G., Kraus, R., Wozny, G.: Extending Documentation-Based Models towards an Efficient Integration into Commercial Process Simulators, Chemie Ingenieur Technik, 86(7), 1117-1129, 2014. [DOI: 10.1002/cite.201400014]
Meyer, K., Zientek, N., Maiwald, M., Kraemer, B., Esche, E., Müller, D., Wozny, G.: Eine robuste Prozessanalytik für die CO2-Abtrennung industrieller Gasströme basierend auf Online-NMR- und -Raman-Spektroskopie, Chemie Ingenieur Technik, 86 (9), 1579, 2014. [DOI: 10.1002/cite.201450076]
Micovic, J., Werth, K., Lutze, P.: Hybrid Separations Combining Distillation and Organic Solvent Nanofiltration for Separation of Wide Boiling Mixtures, Chemical Engineering Research and Design, 92(11), 2131-2147, 2014. [DOI: 10.1016/j.cherd.2014.02.012]
Müller, D., Esche, E., Diana, C., López, C., Wozny, G.: An Algorithm for the Identification and Estimation of Relevant Parameters for Optimization under Uncertainty, Computers & Chemical Engineering, 71(4), 94-103, 2014. [doi:10.1016/j.compchemeng.2014.07.007]
Müller, D., Esche, E., Diana, C., López, C., Wozny, G.: Systematic Parameter Selection for Optimization under Uncertainty, Computer-Aided Chemical Engineering, 717-722, 2014. [doi.org/10.1016/B978-0-444-63433-7.50104-8]
Müller, D., Esche, E., Pogrzeba, T., Hamerla, T., Barz, T., Schomäcker, R., Wozny, G: Hydroformylation of 1-dodecene in Microemulsions: Long-Term Mini-plant Operation Results, Conference Proceedings, 15-24, 2014.
Müller, D., Hoang Minh, D., Merchan, V.A., Arellano-Garcia, H., Kasaka, Y., Müller, M., Schomäcker, R., Wozny, G.: Towards a Novel Process Concept for the Hydroformylation of Higher Alkenes: Mini-plant Operation Strategies via Model Development and Optimal Experimental Design, Chem.Eng.Science, 115, 127-138, 2014. [DOI: 10.1016/j.ces.2013.05.022]
Müller, D., Illner, M., Fleck, A., Esche, E., Barz, T., Schomäcker, R., Wozny, G.: Enabling Online-Optimization for a Multiphase System in a Hydroformylation Mini-plant, Conference Proceedings, 25-36, 2014.
Paul, N., Schrader, P., Enders, S., Kraume, M.: Effects of Phase Behaviour on Mass Transfer in Micellar Liquid/liquid Systems, Chemical Engineering Science, 2014. [doi.org/10.1016/j.ces.2013.02.018]
Pogrzeba, T., Hamerla, T., Müller, D., Wozny, G., Schomäcker, R.: Kontinuierliche Hydroformylierung von 1-Dodecen in wässrigen Mehrphasensystemen mit nichtionischen Tensiden, Chem. Ing. Tech., 86, 1507-1508, 2014. [DOI: 10.1002/cite.201450078]
Pogrzeba, T., Hamerla, T., Schomäcker, R.: Rhodium-Catalyzed Hydroformylation of 1-Dodecene in Microemulsions Systems with Non-Ionic Surfactants, Conference Proceedings, 49-58, 2014.
Rost, A., Brunsch, Y., Behr, A., Schomäcker, R.: Comparison of the Activity of a Rhodium-Biphephos Catalyst in Thermomorphic Solvent Mixtures and Microemulsions, Chemical Engineering & Technology, 37(6), 1055-1064, 2014. [DOI: 10.1002/ceat.201400072]
Schäfer, E., Horbach, F., Enders, S.: Modeling of Liquid and Liquid Interfacial Properties of Binary and Ternary Mixtures, J. Chem. Eng. Data, 59(10), 3003–3016, 2014. [DOI: 10.1021/je500113q]
Schäfer, E., Sadowski, G., Enders, S.: Calculation of Complex Phase Equilibria of DMF/alkane Systems Using the PCP-SAFT Equation of State, Chem. Eng. Sci., 2014. [doi.org/10.1016/j.ces.2013.04.053]
Schäfer, E., Sadowski, G., Enders, S.: Interfacial Tension of Binary Mixtures Exhibiting Azeotropic Behavior: Measurement and Modeling with PCP-SAFT Combined with Density Gradient Theory, Fluid Phase Equilibria, 362, 151-162, 2014. [DOI: 10.1016/j.fluid.2013.09.042]
Schmidt, P., Bednarz, E. L., Lutze, P., Górak, A.: Characterisation of Organic Solvent Nanofiltration Membranes in Multi-component Mixtures: Process Design Workflow for Utilising Targeted Solvent Modifications, Chem. Eng. Sci., 115, 115-126, 2014. [DOI: 10.1016/j.ces.2014.03.029]
Schmidt, P., Micovic, J., Lutze, P., Górak, A.: Organophile Nanofiltration – Herausforderungen und Lösungsansätze zur Anwendung eines innovativen Membrantrennverfahrens, Chemie Ingenieur Technik, 86(5), 602-610, 2014. [DOI: 10.1002/cite.201300153]
Schrader, P., Paasche, C., Enders, S: Phase Behavior of Systems Containing Genapol X080® + Technical 1-dodecene + Water in Comparison with the Phase Behavior of Pure C12E8 + Pure 1-dodecene + Water, Chem. Eng. Sci., 2014. [doi.org/10.1016/j.ces.2013.04.030]
Skale, T., Zedel, D., Carl, A., Kraume, M., von Klitzing, R., Drews, A.: Einfluss von transmembraner Druckdifferenz, Partikelgehalt und Phasenanteil auf das Filtrationsverhalten von Pickering-Emulsionen, Chemie Ingenieur Technik, 86(9), 1528-1529, 2014. [DOI: 10.1002/cite.201450555]
Steimel, J., Harrmann, M., Schembecker, G., Engell, S.: A Framework for the Modeling and Optimization of Process Superstructures under Uncertainty, Chem. Eng. Sci., 115, 225-237, 2014. [DOI: 10.1016/j.ces.2013.04.052]
Sundmacher, K., Górak, A., Kraume, M., Wozny, G.: Special issue: InPROMPT - Integrated Chemical Processes with Liquid Multiphase Systems, Chem. Eng. Sci., 115, 1-2, 2014. [DOI: 10.1016/j.ces.2014.05.034]
Vogelpohl, C., Brandenbusch, C., Sadowski, G.: High-pressure Gas Solubility in Multicomponent Solvent Systems for Hydroformylation. Part II: Syngas SolubilityN. Sup. Sl., 88, 74-84, 2014. [doi:10.1016/j.supflu.2014.01.017]
Wegener, M., Paul, N., Kraume, M.: Fluid Dynamics and Mass Transfer at Single Droplets in Liquid/liquid Systems, International Journal of Heat and Mass Transfer, 71, 475-495, 2014. [DOI: 10.1016/j.ijheatmasstransfer2013.12.024]
Zähringer, K., Wagner, L.-M., Kóvats, P., Thévenin, D.: Experimental characterization of the mass transfer from gas to liquids in a two-phase bubble column, 7th International Berlin Workshop on Transport Phenomena with Moving Boundaries and More, 2014.
Zähringer, K., Wagner, L.-M., Kóvats, P., Thévenin, D.: Experimentelle Charakterisierung des Stofftransports in Mehrphasenreaktoren durch Zwei-Farben-LIF, Chemie Ingenieur Technik, 8, 1527, 2014. [doi.org/10.1002/cite.201450120]
Zagajewski, M., Behr, A., Sasse, P., Wittmann, J.: Continuously Operated Miniplant for the Rhodium Catalyzed Hydroformylation of 1-dodecene in a Thermomorphic Multicomponent Solvent System, Chem. Eng. Sci., 115, 88-94, 2014. [DOI:10.1016/j.ces.2013.09.033]
Zagajewski, M., Dreimann, J., Behr, A.: Verfahrensentwicklung vom Labor zur Miniplant: Hydroformylierung von 1-Dodecen in thermomorphen Lösungsmittelsystemen, Chemie Ingenieur Technik, 86(4), 449-457, 2014. [DOI: 10.1002/cite.201300147]
Zedel, D., Drews, A., Kraume, M.: Comparison of Different Membranes for the Removal of Surfactants from Organic Solvents by Organic Solvent Nanofiltration, Proceedings of 20th International Conference of Process Engineering and Chemical Plant Design 2014, 235-241, Berlin, 2014.
Zhou, T., McBride, K., Zhang, X., Qi, Z., Sundmacher, K.: Integrated Solvent and Process Design Exemplified for a Diels–Alder Reaction, AIChE Journal, 61, 147–158, 2014. [doi.org/10.1002/aic.14630]
Baes, M., Oertel, T., Wagner, C., Weismantel, R.: Mirror-Descents Methods in Mixed Integer Convex Optimization, Springer book series, Algorithms and Combinatorics, 2013. [doi.org/10.1007/978-3-642-38189-8_5]
Beierling, T., Osiander, J., Sadowski, G.: Melt Crystallization of Long-chain Aldehydes from Hydroformylation, Separation and Purification Technology, 2013. [doi.org/10.1016/j.seppur.2013.06.023]
Beierling, T., Sadwoski, G.: Modeling Growth Rates from Static Layer Melt Crystallization, Crystal Growth Design, 2013. [DOI:10.1021/cg400959a]
Bordás, R., Roloff, C., Thévenin, D., Shaw, R.A.: Experimental Determination of Droplet Collision Rates in Turbulence, New journal of physics, 2013. [doi:10.1088/1367-2630/15/4/045010]
Brunsch, Y., Behr, A.: Temperature-Controlled Catalyst Recycling in Homogeneous Transition-Metal Catalysis: Minimization of Catalyst Leaching, Angewandte Chemie, 52(5), 1586-1589, 2013. [DOI: 10.1002/anie.201208667]
Dorn U., Schrader P., Enders S.: Aggregation and Phase Behavior of Nonionic Surfactants (CiEj ) in Aqueous Solution, Vestnik St. Petersburg University, 4(1), 97–113, 2013. [More]
Esche, E., Müller, D., Kraus, R., Wozny, G.: Systematic Approaches for Model Derivation for Optimization Purposes, Chemical Engineering Science, 115, 215-224, 2013. [doi.org/10.1016/j.ces.2013.11.041]
Flassig, R. J., Sundmacher, K.: Optimal Design of Stimulus Experiments for Robust Discrimination of Biochemical Reaction Networks, Bioinformatics, 2013. [doi.org/10.1093/bioinformatics/bts585]
Hamerla, T., Paul, N., Kraume, M., Schomäcker, R.: Mass Transfer Phenomena in Micellar Multiphase Systems Investigated for a Hydroformylation Reaction, Chemie Ingenieur Technik 2013, 85(10), 1530-1539, 2013. [doi.org/10.1002/cite.201300048]
Hamerla, T., Rost, A., Kasaka, Y., Schomäcker, R.: Hydroformylation of 1-Dodecene with Water-Soluble Rhodium Catalysts with Bidentate Ligands in Multiphase Systems, ChemCatChem, 7(5), 1854-1862, 2013. [doi.org/10.1002/cctc.201200744]
Hemmecke, R., Koeppe, M., Weismantel, R.: Graver Basis and Proximity Techniques for Block-structured Separable Convex Integer Minimization Problems, Mathematical Programming A, 145(1-2), 1-18, 2013. [doi.org/10.1007/s10107-013-0638-z]
Hentschel, B., Peschel, A., Freund, H., Sundmacher, K.: Simultaneous Design of the Optimal Reaction and Process Concept for Multiphase Systems, Chem.Eng.Science, 2013. [doi.org/10.1016/j.ces.2013.09.046]
Hentschel, B., Peschel, A., Xie, M., Vogelpohl, C., Sadowski, G., Freund, H., Sundmacher, K.: Model-based Prediction of Optimal Conditions for 1-Octene Hydroformylation, Chem.Eng.Science, 2013. [doi.org/10.1016/j.ces.2013.03.051]
Hoang Minh, D., Barz, T., Merchan, V.A., Biegler, L.T., Arellano-Garcia, H.: Simultaneous Solution Approach to Model-based Experimental Design, AIChE-Journal, 2013. [https://doi.org/10.1002/aic.14145]
Kiedorf, G., Hoang, D.M., Müller, A., Jörke, A., Markert, J., Arellano-Garcia, H., Seidel-Morgenstern, A., Hamel, C.: Kinetics of 1-Dodecene Hydroformylation in a Thermomorphic Solvent System Using a Rhodium-Biphephos Catalyst, Chemical Engineering Science, 145, 31-48, 2013. [doi.org/10.1016/j.ces.2013.06.027]
Kraume, M.: Integrated Chemical Processes in Liquid Multiphase Systems [Integrierte chemische Prozesse in flüssigen Mehrphasensystemen], Chemie Ingenieur Technik, 85(10), 1499-1511, DOI:10.1002/cite.201300013, 2013. [doi.org/10.1002/cite.201300013]
Markert, J., Brunsch, Y., Munkelt, T., Kiedorf, G., Behr, A., Hamel, C., Seidel-Morgenstern A.: Analysis of the Reaction Network for the Rh-Catalyzed Hydroformylation of 1-Dodecene Based on Perturbed Semibatch Experiments, Applied Catalysis A: General, 462-463, 287-295, 2013. [doi.org/10.1016/j.apcata.2013.04.005]
Müller, M., Kasaka, Y., Müller, D., Schomäcker, R., Wozny, G.: Process Design for the Separation of Three Liquid Phases for a Continuous Hydroformylation Process in a Miniplant Scale, Ind. Eng. Chem. Res., 52(22), 7259-7264, 2013. [DOI: 10.1021/ie302487m]
Nowothnik, H., Rost, A., Hamerla, T., Schomäcker, R., Müller, C., Vogt, D.: Comparison of Phase Transfer Agents in the Aqueous Biphasic Hydroformylation of Higher Alkenes, RSC Catal. Sci. Technol., 3, 600-605, 2013. [DOI: 10.1039/C2CY20629C]
Rost, A., Brunsch, Y., Schomäcker, R., Behr, A.: Comparison of Thermomorphic Solvent Mixtures and Microemulsions as Tunable Solvent Systems for the Highly Regioselective Hydroformylation of Long-chain Olefins using a Rhodium-BiPhePhos-Catalyst System, Applied Catalysis A, 2013.
Rost, A., Müller, M., Hamerla, T., Schomäcker, R., Wozny, G: Development of a Continuous Process for the Hydroformylation of Long Chain Olefins in Aqueous Multiphase Systems, J. Chem. Eng. 67, 130-135, 2013. [doi.org/10.1016/j.cep.2012.10.001]
Schäfer, E., Vogelpohl, C., Brandenbusch, C., Sadowski, G., Enders, S.: Simultane Modellierung von Phasengleichgewichten und Grenzflächeneigenschaften mit Hilfe des PCP-SAFT Modells, Chemical Engineering Science, 2013. [doi.org/10.1002/cite.201300036]
Schrader, P., Culaguin-Chicaroux, A., Enders, S.: Phase Behavior of the Water + Nonionic Surfactant (C12E8)+1-Dodecene Ternary System across a Wide Temperature Range, Chemical Engineering Science, 93,131–139, 2013. [doi.org/10.1016/j.ces.2012.08.020]
Vogelpohl, C., Brandenbusch, C., Sadowski, G.: High-pressure Gas Solubility in Multicomponent Solvent Systems for Hydroformylation. Part I: Carbon Monoxide Solubility, Supercritical Fluids, 81, 23-32, 2014. [doi.org/10.1016/j.supflu.2013.04.006]
Baes, M., Del Pia, A., Nesterov, Y., Onn, S., Weismantel, R.: Minimizing Lipschitz-Continuous Strongly Convex Functions over Integer Points in Polytopes, Mathematical Programming, Ser. B, 134, 305-322, 2012. [DOI 10.1007/s10107-012-0545-8]
Behr, A., Brunsch, Y., Lux, A.: Rhodium Nanoparticles as Catalysts in the Hydroformylation of 1-Dodecene and their Recycling in Thermomorphic Solvent Systems, Tetrahedron Letters, 2012. [doi.org/10.1016/j.tetlet.2012.03.062]
Behr, A., Witte, H., Zagajewski, M.: Scale-up durch Miniplant-Technik: Anwendungsbeispiele aus der homogenen Katalyse, Chemie Ingenieur Technik, 2012. [doi.org/10.1002/cite.201100169]
Bordás, R., John, V. Schmeyer, E., Thévenin, D.: Measurement and Simulation of a Droplet Population in a Turbulent Flow Field, Computer and Fluids, 2012. [doi.org/10.1016/j.compfluid.2012.05.003]
Bordás, R., Seshadhri, S., Janiga, G., Skalej, M., Thévenin, D.: Experimental Validation of Numerical Simulations on a Cerebral Aneurysm Phantom Model, Interv. Med. App. Sci., 2012. [doi:10.1556/IMAS.4.2012.4.4.]
Hamerla, T., Schwarze, M., Schomäcker, R.: Catalysis in Modified Liquid-Liquid Multiphase Systems, Chemie Ingenieur Technik, 2012. [doi.org/10.1002/cite.201200043]
Hoang Minh, D., Wozny, G., Brunsch, Y., Behr, A., Markert, J., Hamel, J., Seidel-Morgenstern, A., Arellano-Garcia, H.: Model-Based Optimal Design of Experiments for Determining Reaction Network Structures, Computer Aided Chemical Engineering, 31, 705-709, 2012. [doi.org/10.1016/B978-0-444-59507-2.50133-5]
Fuegenschuh, A., Hayn, C., Michaels, D.: Mixed-Integer Linear Methods for Layout-Optimization of Screening Systems in Recovered Paper Production, Optimization and Engineering, 2012. [doi.10.1007/s11081-014-9249-7]
Lehwald, A., Janiga, G., Thévenin, D., Zähringer, K.: Simultaneous Investigation of Macro- and Micro-mixing in a Static Mixer, Chem. Eng. Science, 2012. [doi.org/10.1016/j.ces.2012.05.026]
Maaß, S., Paul, N., Kraume, M.: Influence of the Dispersed Phase Fraction on Experimental and Predicted Drop Size Distributions in Breakage Dominated Stirred Systems, Chemical Engineering Science, 76, 140-153, 2012 [DOI: 10.1016/j.ces.2012.03.050]
Micovic, J., Beierling, T. Lutze, P., Sadowski, G., Górak, A.: Design of Hybrid Distillation/Melt Crystallisation Processes for Separation of Close Boiling Mixtures, Chemical Engineering and Processing: Process Intensification, 2012. [doi.org/10.1016/j.cep.2012.07.012]
Micovic, J., Beierling, T. Lutze, P., Sadowski, G., Górak, A.: Eine Entwurfsmethode zur Auslegung hybrider Trennverfahren aus Rektifikation und Schmelzekristallisation für die Aufreinigung engsiedender Gemische, Chemie Ingenieur Technik, 2012. [More]
Müller, M., Kasaka, Y., Müller, D., Schomäcker, R., Wozny, G.: A Continuous Hydroformylation Process in a Miniplant Scale: Equipment Design for the Separation of Three Liquid Phases, Computer Aided Chemical Engineering, 31, 710-714, 2012. [doi.org/10.1016/B978-0-444-59507-2.50134-7]
Nguyen, L.A.T., Minding, M., Schwarze, M., Drews, A., Schomäcker, R., Kraume, M.: Adsorption and Filtration Behaviour of Non-ionic Surfactants During Reverse Micellar-enhanced Ultrafiltration, Journal Of Membrane Science, 433, 80-87, 2012. [doi.org/10.1016/j.memsci.2013.01.019]
Nguyen, L.A.T., Schwarze, M., Drews, A., Schomäcker, R., Kraume, M., Böhm, L.: Influence of Non-ionic Surfactants on Reverse Micellar-enhanced Ultrafiltration, Procedia Engineering, 44, 1692-1694, 2012.
Peschel, A., Hentschel, B., Freund, H., Sundmacher, K.: Design of Optimal Multiphase Reactors Exemplifed on the Hydroformylation of Long Chain Alkenes, Chemical Engineering Journal, 188, 126-141, 2012. [doi.org/10.1016/j.cej.2012.01.123]
Rost, A., Brunsch, Y., Schomäcker, R., Behr, A.: Tunable Solvent Systems for the Highly Regioselective Hydroformylation of Long Chain Olefins using a Rhodium-BiPhePhos-catalyst System, Applied Catalysis A, 2012.
Rost, A., Müller, M., Hamerla, T., Kasaka, Y., Wozny, G., Schomäcker, R.: Development of a Continuous Process for the Hydroformylation of Long Chain Olefins in Aqueous Multiphase Systems, Chemical Engineering and Processing, 67, 130-135, 2012. [http://dx.doi.org/10.1016/j.cep.2012.10.001]
Rüther, F., Beierling, T.: Separation of the Isomeric Long-chain Aldehydes Dodecanal/2-methylundecanal via Layer Melt Crystallization, Chemical Engineering Science, 77, 71-77, 2012. [doi.org/10.1016/j.ces.2012.01.055]
Schmidt, P., Köse, T., Lutze, P.: Characterisation of Organic Solvent Nanofiltration Membranes in Multi-component Mixtures: Membrane Rejection Maps and Membrane Selectivity Maps for Conceptual Process Design, Journal of Membrane Science, 429, 103-120, 2012. [doi.org/10.1016/j.memsci.2012.11.031]
Schäfer, E., Sadowski, G.: Liquid-liquid Equilibria of Systems with Linear Aldehydes. Experimental Data and Modeling with PCP-SAFT, Ind. Eng. Chem. Res., 51 (44), 14525–14534, 2012. [DOI: 10.1021/ie301566d]
Schäfer, E., Sadowski, G., Brunsch, Y., Behr, A.: Hydroformylation of 1-Dodecene in the Thermomorphic Solvent System DMF/Decane. Phase Behavior - Reaction Performance - Catalyst Recycling, Ind. Eng. Chem. Res, 51 (31), 10296–10306, 2012. [DOI: 10.1021/ie300484q]
Schwarze, M., Schmidt, M., Nguyen, L.A.T., Drews, A., Kraume, M., Schomäcker, R.: Micellar Enhanced Ultrafiltration of a Rhodium Catalyst, Journal of Membrane Science, 421–422, 165-171, 2012. [doi.org/10.1016/j.memsci.2012.07.017]
Steimel, J, Engell, S.: A Framework for the Modeling and Optimization of Process Superstructures under Uncertainty, Chemical Engineering Science, 115, 225-237, 2012. [doi.org/10.1016/j.ces.2013.04.052]
Zagajewski, M., Behr, A., Sasse, P., Wittmann, J.: Continuously Operated Miniplant for the Rhodium Catalyzed Hydroformylation of 1-Dodecene in a Thermomorphic Multicomponent Solvent System (TMS), Special Issue InPROMPT, 2012.
Barz, T., Kraus, R., Zhu, L., Wozny, G., Arellano-Garcia, H.: Generation of Discrete First- and Second-Order Sensitivities for Single Shooting, AIChE Journal, 2011. [doi.org/10.1002/aic.13720]
Barz, T., Zhu, L., Wozny, G., Arellano-Garcia, H.: Efficient Computation of First- and Second-Order Sesitivties Using an Internal Forward Differentiation Scheme, Computer Aided Chemical Engineering, 29, 733-737, 2011. [doi.org/10.1016/B978-0-444-53711-9.50147-4]
Heidbrecht, P., Pfafferodt, M., Sundmacher, K.: Multiscale Modelling Strategy for Structured Catalytic Reactors, Chemical Engineering Science, 66(19), 4389-4402, 2011. [DOI: 10.1016/j.ces.2011.03.052]
Kuntsche, S.; Manenti, F.; Buzzi-Ferraris, G.; Wozny, G.: Modelling in the Documentation Level using MOSAIC and Numerical Libraries, AIDIC Conference Series, 10, 2011. [More]
Kuntsche, S., Arellano-Garcia, H., Wozny, G.: MOSAIC, an Environment for Web-based Modelling in the Documentation Level, Computer Aided Chemical Engineering, 29, 1140-1144, 2011. [doi.org/10.1016/B978-0-444-54298-4.50007-6]
Kuntsche, S., Barz, T., Kraus, R., Arellano-Garcia, H., Wozny, G.: MOSAIC a Web-based Modeling Environment for Code Generation, Computers & Chemical Engineering, 35(11), 2257-2273, 2011. [doi.org/10.1016/j.compchemeng.2011.03.022]
Kuntsche, S., Kraus, R., Arellano-Garcia, H., Wozny, G.: MOSAIC, an Internet Tool for Cooperative Modeling in the Documentation Level and Code Generation, Chemical Engineering Transactions, 2011. [More]
Merchan Restrepo, V. A., Kuntsche, S., Arellano-Garcia, H., Wozny, G.: Symbolic Generation of First and Higher-order Derivatives with MOSAIC, 18th International Process Engineering and Chemical Plant Design, Berlin, 2011.
Paul, N., Kraume, M.: Influence of Surfactants on Fluid Dynamics and Mass Transfer of Single Droplets, 18th International Process Engineering and Chemical Plant Design, Berlin, 2011. [More]
Peschel. A.; Hentschel, B.; Freund, HJ; Sundmacher, K.: Optimal Reactor Design for the Hydroformylation of Long Chain Alkenes in Biphasic Liquid Systems. Computer Aided Chemical Engineering, 29, 1246-1250, 2011. [doi.org/10.1016/B978-0-444-54298-4.50028-3]
Schomäcker, R., Nowothnick, H., Schwarze, M., Rost, A., Hamerla, T.,: Mizellare Lösungen und Mikroemulsionen als Reaktionsmedien für katalytische Reaktionen, Chemie Ingenieur Technik, 83(9), 1-14, 2011. [DOI:10.1002/cite.201100042]
Schrader, P., Dorn, U., Kulaguin-Chicaroux, A., Enders, S.: Phase Equilibria of Surfactant Containing Systems, Process Engineering and Chemical Plant Design, (Eds.: Wozny, G., Hady, L.), Universitätsverlag der TU Berlin, 2011. [doi.org/10.14279/depositonce-3011]
Schrader, P., Dorn, U., Kulaguin-Chicaroux, A., Enders, S.: Phase Equilibria of Surfactant Containing Systems, ECCE, Berlin, 2011. [More]
Tometzki, T., Engell, S.: Systematic Initialization Techniques for Hybrid Evolutionary Algorithms for Solving Two-Stage Stochastic Mixed-Integer Programs, IEEE Transactions on Evolutionary Computation, 15(2), 196-214, 2011. [DOI: 10.1109/TEVC.2010.2058121]
Urselmann, M., Barkmann, S., Sand, G., Engell, S.: A Memetic Algorithm for Global Optimization in Chemical Process Synthesis Problems, IEEE Transactions on Evolutionary Computation - Special Issue on Advances in Memetic Computation 15(5), 659-683, DOI: 10.1109/TEVC.2011.2150753, 2011. [DOI:10.1109/TEVC.2011.2150753]
Urselmann, M., Engell, S.: Optimization-based Design of Reactive Distillation Columns Using a Memetic Algorithm, Computers and Chemical Engineering, 2011. [doi.org/10.1016/j.compchemeng.2011.01.038]
Buchheim, C., Michaels, D., Weismantel, R.: Integer Programming Subject to Monomial Constraints, SIAM J. Optim., 20(6), 3297-3311, 2010. [doi.org/10.1137/090764402]
Drews,A., Arellano-Garcia, H., Schomäcker, R., Kraume, M., Wozny, G.; Ultrafiltration of Surfactant Micelles: Cross-flow Experiments and Flux Modelling, Proc. ESCAPE-20, 20th European Symposium on Computer Aided Process Engineering, Ischia/Italien, 2010, Computer Aided Chemical Engineering, 28, 787-792, 2010. [doi.org/10.1016/S1570-7946(10)28132-4]
Kraus, R., Arellano-Garcia, H., Wozny, G.: A Novel Process Concept for the Production of Ethyl Lactate, Distillation Absorption 2010, 2010. [More]
Schwarze, M., Le, D.K., Wille, S., Drews, A., Arlt, W., Schomäcker, R.: Stirred Cell Ultrafiltration of Aqueous Micellar TX-100 Solutions, Separation Science and Technology, 74, 21-27, 2010. [doi.org/10.1016/j.seppur.2010.05.003]
Tometzki, T., Engell, S.: Risk Conscious Solution of Planning Problems under Uncertainty by Hybrid-Multi-Objective Evolutionary Algorithms, Computers & Chemical Engineering 35(11), 2521-2539, 2010. [DOI: 10.1016/j.compchemeng.2011.01.044]